2-Chloro-1,2-diphenylethanone (desyl chloride)
نویسندگان
چکیده
The title compound, C(14)H(11)ClO, is a racemic derivative of benzoin. Its carbonyl group adopts a nearly eclipsed conformation with the Cl substituent characterized by a dihedral angle of 17.5 (2)°. The closest intermolecular π-π contact is 4.258 (1) Å.
منابع مشابه
2-(4-Methoxy-2-methylanilino)-1,2-diphenylethanone
The title compound, C(22)H(21)NO(2), was synthesized from 4-meth-oxy-2-methyl-aniline and 2-hy-droxy-1,2-diphenyl-ethanone. In the title compound, the C-C-C-N-C backbone adopts an all-trans conformation. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen-bond inter-actions.
متن کاملStructural characterization of two benzene-1,2-diamine complexes of zinc chloride: a molecular compound and a co-crystal salt
The structures of two zinc complexes containing bidentate benzene-1,2-di-amine ligands are reported. (Benzene-1,2-di-amine-κ(2) N,N')di-chloro-idozinc, [ZnCl2(C6H8N2)], (I), displays a distorted tetra-hedral coordination sphere for the metal cation. The di-amine ligand and the Zn atom reside on a crystallographic mirror plane. In the 1:1 co-crystal salt trans-di-aqua-bis-(4,5-di-methyl-benzene-...
متن کاملA Qualitative Comparison of the Reactivities of 3,4,4,5-Tetrachloro-4H-1,2,6-thiadiazine and 4,5-Dichloro-1,2,3-dithiazolium Chloride.
The high yielding transformations of 3,4,4,5-tetrachloro-4H-1,2,6-thiadiazine into 3,5-dichloro-4H-1,2,6-thiadiazin-4-one (up to 85%) and 2-(3,5-dichloro-4H-1,2,6-thiadiazin-4-ylidene)malononitrile (up to 83%) have been investigated and compared to the analogous transformations of the closely-related 4,5-dichloro-1,2,3-dithiazolium chloride (Appel's salt) into 4-chloro-5H-1,2,3-dithiazol-5-one ...
متن کاملCometabolic degradation of mono-chloro benzoic acids by Rhodococcus sp. R04 grown on organic carbon sources
The aerobic cometabolism of chlorobenzoic acids (CBAs) by Rhodococcus sp. R04 was accomplished by augmenting the medium with organic carbon sources. In mineral medium supplemented with glucose (MMG), 0.5 mM 2-CBA was incompletely metabolized after the 5day incubation, while the near-complete disappearance of 0.5 mM 4-CBA was monitored. Over the 5-day incubation period, the concentration of chlo...
متن کاملCrystal structure of ({(1R,2R)-N,N′-bis[(quinolin-2-yl)methyl]cyclohexane-1,2-diamine}chloridoiron(III))-μ-oxido-[trichloridoferrate(III)] chloroform monosolvate
The first FeIII atom in the solvated title compound, [Fe2Cl4O(C26H28N4)]·CHCl3, adopts a distorted six-coordinate octa-hedral geometry. It is coordinated by one chloride ligand, four N atoms from the (1R,2R)-N,N'-bis-[(quinolin-2-yl)methyl]cyclo-hexane-1,2-di-amine ligand, and a bridging oxido ligand attached to the second FeIII atom, which is also bonded to three chloride ions. A very weak int...
متن کامل